Electrolysis and permanganate (PM) oxidation are two commonly used technologies for water treatment. However, they are often handicapped by their slow reaction rates. To improve the removal efficiency of refractory contaminants, we combined electrolysis with PM using an activated carbon fiber (ACF) as cathode (E-ACF-PM) for the first time to treat diclofenac (DCF) in aqueous solution. Up to 90% DCF was removed in 5 min by E-ACF-PM process. In comparison, only 3.95 and 27.35% of DCF was removed by individual electrolysis and PM oxidation at the same time, respectively. Acidic condition was more conducive to DCF removal. Surprisingly, soluble Mn(III) _{( aq)} formed on the surface of ACF was demonstrated as the principal oxidizing agent in E-ACF-PM process. Further studies showed that all three components (electrolysis + ACF + PM) were necessary to facilitate the heterogeneous generation of reactive Mn(III) _{( aq)}. Moreover, SEM images and XPS spectra of ACF before and after treatment revealed that the morphologies and elemental compositions of reacted ACF were nearly unchanged during the E-ACF-PM process. ACF can be remained active and utilized to the rapid degradation of DCF in E-ACF-PM process even after reused for 20 times. Therefore, the E-ACF-PM process may provide a novel and effective alternative on the generation of reactive Mn(III) _{( aq)} in situ for water treatment by green electrochemical reactions.

We examine urban flood response through data-driven analyses for a diverse sample of “small” watersheds (basin scale ranging from 7.0 to 111.1 km²) in the Charlotte Metropolitan region. These watersheds have experienced extensive urbanization and suburban development since the 1960s. The objective of this study is to develop a broad characterization of land surface and hydrometeorological controls of urban flood hydrology. Our analyses are based on peaks-over-threshold flood data developed from USGS streamflow observations and are motivated by problems of flood hazard characterization for urban regions. We examine flood-producing rainfall using high-resolution (1 km² spatial resolution and 15 min time resolution), bias-corrected radar rainfall fields that are developed through the Hydro-NEXRAD system. The analyses focus on the 2001–2015 period. The results highlight the complexities of urban flood response. There are striking spatial heterogeneities in flood peak magnitudes, response times, and runoff ratios across the study region. These spatial heterogeneities are mainly linked to watershed scale, the distribution of impervious cover, and storm water management. Contrasting land surface properties also determine the mixture of flood-generating mechanisms for a particular watershed. Warm-season thunderstorm systems and tropical cyclones are main flood agents in Charlotte, with winter/spring storms playing a role in less-urbanized watersheds. The mixture of flood agents exerts a strong impact on the upper tail of flood frequency distributions. Antecedent watershed wetness plays a minor role in urban flood response, compared with less-urbanized watersheds. Implications for flood hazard characterization in urban watersheds and for advances in flood science are discussed.