Virtual coupling is regarded as an efficient way to improve the line capacity of rail transportation systems by reducing the spacing between consecutive trains. This paper is the first to compare and assess different distributed model predictive control (MPC) approaches, i.e., cooperative distributed MPC, serial distributed MPC, and decentralized MPC, for virtually coupled trains with a nonlinear train dynamic model. To make a balanced trade-off between computational complexity and efficiency, we also propose and assess convex approximations of the above control approaches. Furthermore, we are the first to introduce the relaxed dynamic programming approach to analyze the stability of the MPC-based nonlinear train control problem. By using the relaxed dynamic programming approach, a distributed stopping criterion with a stability guarantee is developed for the cooperative distributed MPC approach. In real life, masses of trains are different and can change at stations due to changes in passenger loads. This change in mass can significantly affect the dynamics and control of the virtually coupled trains when not taken into account in the control design. Therefore, we explicitly consider heterogeneous train masses when designing MPC approaches. We evaluate the different distributed MPC approaches through case studies based on the data of the Beijing Yizhuang Line. Simulation results indicate that the cooperative distributed MPC approach has the best tracking performance, while the serial distributed MPC approach can reduce communication requirements and computation capabilities with sacrifices of tracking performance.