The normalized radar cross section (NRCS) measured by satellite ocean radar systems is representative of the sea surface roughness at the scale of gravity-capillary waves, which are not only dominated by winds, but also modulated by some secondary factors such as sea surface temperature (SST) and sea surface salinity (SSS). In this paper, the variations of NRCS due to SST changes, depending on scatterometer radar frequency, polarization, and incidence angle, are investigated on the basis of a physics-based radar backscatter model and a dataset of collocated ASCAT C-band and RapidScat Ku-band scatterometer measurements. The study shows that the SST effects are substantial at Ku-band, but rather negligible for C-band NRCS measurements. Furthermore, the SST effects are wind speed dependent and more pronounced in VV polarization and at higher incidence angles. SSS effects, due to dielectric constant, surface tension, and dynamic viscosity variations, on scatterometer winds are limited (within 1%). This study concludes that it is necessary to take SST into account in scatterometer wind retrieval for radar wavelengths smaller than C-band.