Compositional data on vegetable biomass is widely available from research papers and online databases. However, the high diversity of biomass characteristics and composition represents a challenge for researchers and companies willing to produce novel substances from residues, and that should decide on the best and most feasible options for their use as feedstocks. The present study constructed a database with information gathered from the proximate, ultimate, and chemical composition of different biomass residues that can be used for data analysis and classification to elucidate better how they can be valorized. Different data clustering techniques were implemented to determine how compositional data can be segmented. The identified groups, that contained residues with similar characteristics, allowed to have an insight into the valorization of these biomasses, which can be used as an initial tool for biorefinery design. The use of data clustering facilitated the identification of different types of biomasses in a systematic way, which until now has not been reported in the literature.