Graphene transparent electrode (GTE) has been attracting much attention due to fascinating physical properties. However, the extensive deployment of copper foil within GTE production has imparted substantial environmental burden. This paper is a cradle-to-gate life cycle assessment (LCA) study to investigate the environmental impacts of roll-to-roll produced chemical vapor deposition (CVD) GTE and the environmental potential of recycling copper foil for cleaner production. Four production scenarios are developed to promote the lab-to-fab progress, including lab scenario, industry baseline scenario, industry recycling scenario and microwave plasma chemical CVD scenario. The functional unit is set as 1 m2 of the GTE production and the life cycle inventories of different scenarios are explored. Results show that the copper foil is a major contributor in baseline scenario in the category of primary energy consumption and global warming. The impacts of GTE production in industry recycling scenario vary from 0.01 to 0.18 of the values in industry baseline scenario. Therefore, copper foil recycling shows environmental potential for GTE production. If all building integrated photovoltaics transition to employing perovskite solar cells with GTE produced in copper recycling scenario, the potential reduction in CO2 emissions is estimated at 141.2 million kilograms per year. The findings serve as a roadmap for the industry, highlighting key areas where improvements can be made to upscale production while minimizing environmental impact. This paper provides insights into the major environmental contributors in the GTE production, guiding the upscaling routes for cleaner GTE production in the future.