The polarization state of starlight reflected by a planetary atmosphere uniquely reveals coverage, particle size, and composition of aerosols as well as changing cloud patterns. It is not possible to obtain a comparable level of detail from flux-only observations. It is therefore a powerful tool to better understand the crucial role played by clouds and aerosols in the chemistry, dynamics, and radiative balance of a planet. Furthermore, polarization observations can probe the atmosphere of planets independently of the orbital geometry (hence it applies to both transiting and non-transiting exoplanets). A high-resolution spectropolarimeter with a broad wavelength coverage, particularly if attached to a large space telescope, would enable simultaneous study of the polarimetric planetary properties of the continuum and to look for and characterize the polarimetric signal due to scattering from single molecules, providing detailed information about the composition and vertical structure of the atmosphere.

Proxima b is our nearest potentially rocky exoplanet and represents a formidable opportunity for exoplanet science and possibly astrobiology. With an angular separation of only 35 mas (or 0.05 AU) from its host star, Proxima b is however hardly observable with current imaging telescopes and future space-based coronagraphs. One way to separate the photons of the planet from those of its host star is to use an interferometer that can easily resolve such spatial scales. In addition, its proximity to Earth and its favorable contrast ratio compared with its host M dwarf (approximately 10^-5 at 10 microns) makes it an ideal target for a space-based nulling interferometer with relatively small apertures. In this paper, we present the motivation for observing this planet in the mid-infrared (5-20 microns) and the corresponding technological challenges. Then, we describe the concept of a space-based infrared interferometer with relatively small (<1m in diameter) apertures that can measure key details of Proxima b, such as its size, temperature, climate structure, as well as the presence of important atmospheric molecules such as H₂O, CO₂, O₃, and CH₄. Finally, we illustrate the concept by showing realistic observations using synthetic spectra of Proxima b computed with coupled climate chemistry models.