Light management strategies using photonic crystals have been proven to efficiently improve light harvesting and subsequently conversion efficiency of various optoelectronic devices. This study focuses on 3D inverse opal CH3NH3PbI3 photoanodes in perovskite solar cells from a combined numerical and experimental approach. Varying the pore size and the layer thickness in numerical simulations, we first determined theoretical optimum from a purely optical point of view. Corresponding 3D inverse opal photonic nanostructures were then fabricated through spin-coating protocols using polystyrene nanospheres of various diameters as hard templating sacrificial agents. It demonstrates how the photonic nanostructuration of the perovskite layer impacts both optical and electronic properties of experimental samples. Regarding the individual 3D inverse opal perovskite layers, an optimum of light absorption is reached for an ∼500 nm diameter pore photonic nanostructure, with a photonic absorption enhancement as high as 16.1% compared to an unstructured compact benchmark. However, in addition to electronic-related countereffects, local light absorption in the hole transporting material is observed in assembled solar cells, weakening the light management benefits of the perovskite layer nanostructuration to only ∼3% photonic enhancement.

Complete absorption of electromagnetic waves is paramount in today's applications, ranging from photovoltaics to cross-talk prevention into sensitive devices. In this context, we use a genetic algorithm (GA) strategy to optimize absorption properties of periodic arrays of truncated square-based pyramids made of alternating stacks of metal/dielectric layers. We target ultra-broadband quasi-perfect absorption of normally incident electromagnetic radiations in the visible and near-infrared ranges (wavelength comprised between 420 and 1600 nm). We compare the results one can obtain by considering one, two or three stacks of either Ni, Ti, Al, Cr, Ag, Cu, Au orWfor the metal, and poly(methyl methacrylate) (PMMA) for the dielectric. More than 1017 configurations of geometrical parameters are explored and reduced to a few optimal ones. This extensive study shows that Ni/PMMA, Ti/PMMA, Cr/PMMA and W/PMMA provide high-quality solutions with an integrated absorptance higher than 99% over the considered wavelength range, when considering realistic implementation of these ultra-broadband perfect electromagnetic absorbers. Robustness of optimal solutions with respect to geometrical parameters is investigated and local absorption maps are provided. Moreover, we confirm that these optimal solutions maintain quasi-perfect broadband absorption properties over a broad angular range when changing the inclination of the incident radiation. The study also reveals that noble metals (Au, Ag, Cu) do not provide the highest performance for the present application.

Vortex phase masks have been shown to be an efficient means to reduce the blinding stellar light in high-contrast imaging instruments. Once placed at the focal plane of the telescope, the helical phase ramp of a vortex phase mask diffracts the light of a bright on-axis source outside the re-imaged telescope pupil, while transmitting the light of a faint off-axis companion nearly unaffected. The Annular Groove Phase Mask (AGPM) is a broadband metasurface implementation of a vector vortex phase mask using the artificial birefringence of a circular subwavelength grating etched onto a diamond substrate. To date, the AGPM design has been optimized using rigorous coupled-wave analysis (RCWA), which is a valid tool to simulate periodic straight gratings. However, we have now reached a performance level where the curvature of the grating lines at the center becomes a limiting factor. Here, we use a finite-difference time-domain (FDTD) method to correctly describe the AGPM performance, including the effect of the curved grating close to its center. We confirm the validity of this simulation framework by comparing its predictions with experimental results obtained on our infrared coronagraphic test bench, and we show that RCWA fails at reproducing correctly the central AGPM performance, confirming the need for a full 3d simulation tool such as FDTD. Finally, we use FDTD to optimize the grating parameters at the AGPM center, and conclude with a new optimal design.

Photonic structuration is an efficient way to improve light harvesting in multiple optoelectronic applications. In this study, photonically structured TiO2 is considered as a photoanode layer for perovskite solar cells to enhance light absorption through the excitation of quasi-guided modes within the photoactive perovskite material, while optimizing the charge collection in the photovoltaic assembly and therefore its global efficiency. Practically, polystyrene beads of various diameters are used as hard templating sacrificial agents for the design of inverse-opal TiO2 through spin-coating protocols. The positive impact of the porous photonic structuration in comparison with compact, unstructured photoactive layers is demonstrated. An optimum of light absorption is shown for hybrid TiO2-perovskite structures composed of ∼400 nm diameter TiO2 hollow spheres filled with CH3NH3PbI3, confirming recent numerical predictions. However, electronic-related countereffects are observed in consecutively assembled solar cells when pore dimensions exceed the estimated diffusion length of electrons in the infiltrated perovskite material. Upper conversion efficiency is obtained with solar cells composed of ∼220 nm diameter large TiO2 pores filled with CH3NH3PbI3.

Light management is an important area of photovoltaic research, but little is known about it in perovskite solar cells. The present work numerically studies the positive effect of structuring the photo-active layer of perovskite material. This structuration consists of a hybrid absorbing layer made of an uniform part and an opal-like part. A genetic algorithm approach allows us to determine the optimal combination among more than 1.4 x 10⁹ potential combinations. The optimal combination provides an internal quantum efficiency of 98.1%, nearly 2% higher than for an equivalent unstructured photo-active layer. The robustness of the optimum against potential experimental deviations, as well as the angular dependency of the proposed structure, are examined in the present study.

High contrast imaging at small inner working angles can be achieved using a vector vortex coronagraph in the focal plane of the telescope providing a helical phase ramp with a singularity at its center. The form birefringence of full-diamond subwavelength gratings has proven to be well suited to manufacture such vortex phase masks for coronagraphic applications (Subwavelength Grating Vortex Coronagraph, SGVC). In the past years our group has developed and manufactured SGVCs of topological charge 2 (Annular Groove Phase Mask, AGPM) made of a concentric diamond subwavelength grating. For future applications including ELT-class telescopes in the near-to mid-infrared that will partly resolve nearby stars, it is however useful to increase the topological charge of the vortex. After shortly reviewing our previous attempts at optimizing the grating structure for SGVC of charge 4, we present the first laboratory results obtained with such devices. We then introduce and discuss more realistic simulations compared to prior studies using finite-difference time-domain methods. The quality of the simulation results obtained with the open source software MEEP for an AGPM is shown to be appropriate for developing and assessing the performance of future vortex phase masks. We therefore perform updated simulations for SGVC of charge 4 including various designs with straight and curved grating lines. We conclude with a perspective on the potential of metasurfaces and their applications to design novel vortex coronagraphs based on subwavelength structures.

Perovskite solar cells have shown a tremendous interest for photovoltaics since the past decade. However, little is known on the influence of light management using photonic crystals inside such structures. We present here numerical simulations showing the effect of photonic crystal structuring on the integrated quantum efficiency of perovskite solar cells. The photo-active layer is made of an opal-like perovskite structure (monolayer, bilayer or trilayer of perovskite spheres) built in a TiO₂ matrix. Fano resonances are exploited in order to enhance the absorption, especially near the bandgap of perovskite material. The excitation of quasi-guided modes inside the absorbing spheres enhances the integrated quantum efficiency and the photonic enhancement factor. More specifically, a photonic enhancement factor as high as 6.4% is predicted in the case of spheres monolayer compared to an unstructured perovskite layer. The influences of sphere’s radius and incident angle on the absorbing properties are also estimated. Those numerical results can be applied to the nascent field of photonic structuring inside perovskite solar cells.