Evaluation of membrane fouling at constant flux and constant transmembrane pressure conditions
Implications for membrane modification
M. Chen (TU Delft - ChemE/Product and Process Engineering, TU Delft - Sanitary Engineering)
LC Rietveld (TU Delft - Sanitary Engineering)
Sebastiaan Heijman (TU Delft - Sanitary Engineering)
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Abstract
Membrane modification is commonly applied in water purification and wastewater treatment to reduce fouling of membranes. However, the influence of fouling test methods on evaluating pristine and modified membranes is often overlooked. This study investigates fouling behavior of alumina and SiC-deposited alumina membranes during oil-in-water emulsion filtration under both constant flux and constant transmembrane pressure conditions. Threshold flux was first determined using flux-stepping experiments, with the 90-min SiC-deposited membrane showing the highest value at 95 L m− 2 h− 1. In single-cycle constant flux tests, fouling trends aligned with threshold flux data. However, when backwash was included, fouling characteristics shifted and depended on the permeate flux. Enhanced hydrophilicity and surface charge improved backwash efficiency in modified membranes. Yet, extensive modification negatively affected performance due to significant permeance loss (>57 %). Under constant pressure, fouling was dominated by internal pore blocking, and backwash efficiency was solely linked to membrane permeance, regardless of surface properties. Thus, constant flux filtration with backwash best reflects operational conditions and is recommended for evaluating membrane modifications.
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