A Biocatalytic Aza-Achmatowicz Reaction
E Fernandez Fueyo (TU Delft - BT/Biocatalysis)
Sabry H.H. Younes (Sohag University, TU Delft - BT/Biocatalysis)
Stefan Van Rootselaar (Radboud Universiteit Nijmegen)
René W M Aben (Radboud Universiteit Nijmegen)
R. Renirie (IVAM UvA BV)
Ron Wever (Universiteit van Amsterdam)
Dirk Holtmann (DECHEMA Research Institute)
Floris P J T Rutjes (Radboud Universiteit Nijmegen)
F. Hollmann (TU Delft - BT/Biocatalysis)
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Abstract
A catalytic, enzyme-initiated (aza-) Achmatowicz reaction is presented. The involvement of a robust vanadium-dependent peroxidase from Curvularia inaequalis allows the simple use of H2O2 and catalytic amounts of bromide.