Characterization of the transitional zone between fully carbonated and non‑carbonated areas in slag-rich cement paste after long-term natural exposure
Y. Zhang (Southeast University, TU Delft - Materials and Environment)
Shan He (TU Delft - Materials and Environment)
X. Liang (TU Delft - Materials and Environment)
M. Minfei (University of Oxford, TU Delft - Materials and Environment)
O. Çopuroǧlu (TU Delft - Materials and Environment)
Erik Schlangen (TU Delft - Materials and Environment)
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Abstract
Due to the gradual diffusion of CO2 under natural exposure, areas with varied degrees of carbonation exist at different depths from the surface of slag-rich cement paste. While extensive research has been dedicated to investigating the fully carbonated zone as identified by phenolphthalein spray, the transitional zone, located between the fully carbonated and the uncarbonated regions, has received comparatively less attention. This study thus aims to address this research gap by exploring its microstructural, micromechanical, and mineralogical properties. The results reveal that carbonation-induced damage extends beyond the fully carbonated zone as identified by phenolphthalein. Particularly in the transitional area close to the carbonated zone, nanoindentations results reveal that micromechanical properties of this area are even lower to that of the fully carbonated zone. In addition, mineralogical investigation suggest that the depth of carbonation stays within the range where slag-containing blends loses its green coloration. By comparing specimens with different slag composition, it was found that the depth of this faded green area can be an important indicator to assess the carbonation resistance of slag-containing blends.
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