Catalysts based on the nanodispersed metastable iron oxyhydroxide, 2-line ferrihydrite
Alexander A. Khassin (Boreskov Institute of Catalysis SB RAS, Novosibirsk State University)
Tatyana P. Minyukova (Boreskov Institute of Catalysis SB RAS)
Lyudmila M. Plyasova (Boreskov Institute of Catalysis SB RAS)
G.A. Filonenko (Novosibirsk State University)
Tamara M. Yurieva (Boreskov Institute of Catalysis SB RAS)
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Abstract
The chapter reviews the data on the 2-line ferrihydrite structure and texture, methods for its preparation, and catalytic properties of 2LFH-based catalysts. Since 2-line ferrihydrite is metastable, the necessity and possibility of inhibiting its crystallization to hematite is discussed and new data on the kinetics of crystallization process are reported, including the effect of Al3+, Cr3+, and Cu2+ promotion. During discussion, particular attention is paid to the potential of 2LFH in catalytic application.
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