Directing role of pH and ethanol vapour on the formation of 2D or 3D mesostructured silica and hybrid organo-silica thin films

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Directing role of pH and ethanol vapour on the formation of 2D or 3D mesostructured silica and hybrid organo-silica thin films

Journal Article (2002)

Author(s)

B. Alonso (CRMHT, CNRS UPR )

A. R. Balkenende (Philips Research Laboratories)

PA Albouy (University of Paris-Sud)

Leyden Durand Lopez (LURE)

F. Babonneau (Université Paris VI)

Affiliation

External organisation

DOI related publication

https://doi.org/10.1039/b205501p

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https://resolver.tudelft.nl/uuid:1b299b66-d13f-433b-b3a9-5cc64407f9a2

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Publication Year

2002

Language

English

Affiliation

External organisation

Issue number

10

Volume number

26

Pages (from-to)

1270-1272

Abstract

A simple synthetic route leading to ordered mesostructured silica and organo-silica thin films is investigated by in situ X-ray experiments. The mesophase directing role of pH and of ethanol vapour pressure during film formation is demonstrated. Modifications of these two parameters during dip coating results in three different 2D or 3D mesostructures (p6mm, P63/mmc, or Pm3n).

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