Making Waves

A sea change in treating wastewater – Why thermodynamics supports resource recovery and recycling

Journal Article (2022)
Author(s)

Xiaodi Hao (Beijing University of Civil Engineering & Architecture)

Daoqi Wu (Beijing University of Civil Engineering & Architecture)

Ji Li (Beijing University of Civil Engineering & Architecture)

Ranbin Liu (Beijing University of Civil Engineering & Architecture)

Mark M.C. van Loosdrecht (Beijing University of Civil Engineering & Architecture, TU Delft - BT/Environmental Biotechnology)

Research Group
BT/Environmental Biotechnology
Copyright
© 2022 Xiaodi Hao, Daoqi Wu, Ji Li, Ranbin Liu, Mark C.M. van Loosdrecht
DOI related publication
https://doi.org/10.1016/j.watres.2022.118516
More Info
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Publication Year
2022
Language
English
Copyright
© 2022 Xiaodi Hao, Daoqi Wu, Ji Li, Ranbin Liu, Mark C.M. van Loosdrecht
Research Group
BT/Environmental Biotechnology
Bibliographical Note
Green Open Access added to TU Delft Institutional Repository 'You share, we take care!' - Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.@en
Volume number
218
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Abstract

Entropy is a concept defined by the second law of thermodynamics. Applying this concept to the world we live in, entropy production must be minimized and negentropy (negative entropy production) should be accelerated, in order to produce a healthy and stable ecological system. The present wastewater treatment, however, contributes to entropy production. This means that conventional wastewater treatment, without recovery of resource and energy, will gradually but inevitably contribute to a deteriorating ecological balance. When the self-cleaning ability of the natural ecological system is limited, the need to develop sustainable wastewater treatment in order to delay entropy production and accelerate negentropy becomes urgent. Resource and energy recovery from wastewater should be the first priority, as they can contribute significantly towards minimizing entropy production and accelerating negentropy. Sustainable wastewater treatment must focus on recovering recyclable high value-added organic chemicals from wastewater and/or excess sludge to minimize entropy production caused by methane (CH4, once combusted, is converted into CO2 - an even higher substance in entropy) via anaerobic digestion. Instead of CH4, thermal energy present in the effluent can be utilized for heating/cooling buildings and also for drying excess sludge towards incineration to recover more energy. Overall, this can lead to a carbon-neutral operation and even creating a “carbon sink” could be possible for wastewater treatment.

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