Ferrocene-decorated graphene nanosheets built by edge-to-face π-π interaction for room temperature ppb-level NO sensing
Lulu Zhang (South China Normal University)
Yixun Gao (South China Normal University)
Yancong Feng (South China Normal University)
Zhijian Mai (South China Normal University)
Jianqiang Wang (South China Normal University)
Yanwei Chang (South China Normal University)
Fengnan Wang (The First Affiliated Hospital of Guangzhou Medical University)
Peerasak Paoprasert (Thammasat University)
Paddy J. French (TU Delft - Bio-Electronics)
undefined More Authors (External organisation)
More Info
expand_more
Other than for strictly personal use, it is not permitted to download, forward or distribute the text or part of it, without the consent of the author(s) and/or copyright holder(s), unless the work is under an open content license such as Creative Commons.
Abstract
The development of materials toward ppb-level nitric oxide (NO) sensing at room temperature remains in high demand for the monitoring of respiratory inflammatory diseases. In order to find an iron-containing molecule without steric hindrance to combine with graphene for room temperature NO gas sensing, here a supramolecular assembly of ferrocene (Fc) and reduced graphene oxide (rGO) was designed and prepared for NO sensing. The assembly of Fc/rGO was characterized using FT-IR, TEM, and XPS measurements. The Fc/rGO-based sensors exhibited superior NO sensing properties at room temperature including high response (Ra/Rg = 1.73, 1 ppm), high selectivity against other exhaled gases, reliable repeatability and stability (less than 4 % decrease after 40 days). A practical limit of detection (LOD) of 200 ppb was achieved. The theoretical simulation demonstrates that ferrocene is assembled via π-π interaction with rGO in edge-to-face configuration which provides relatively lower energy than face-to-face configuration does for the whole assembly. It was first verified that the enhanced adsorption capacity and the charge transfer between NO and Fc/rGO would result in improvement of the assembly's sensitivity toward NO after ferrocene was assembled with graphene. This work provides a fresh approach of anchoring iron on graphene for gas sensing via supramolecular methods.