Cerium-loaded algae exoskeletons for active corrosion protection of coated AA2024-T3

Journal Article (2017)
Author(s)

Paul J. Denissen (TU Delft - Aerospace Engineering)

Santiago J. Garcia (TU Delft - Aerospace Engineering)

Research Group
Novel Aerospace Materials
DOI related publication
https://doi.org/10.1016/j.corsci.2017.09.019 Final published version
More Info
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Publication Year
2017
Language
English
Research Group
Novel Aerospace Materials
Volume number
128
Pages (from-to)
164-175
Downloads counter
163

Abstract

The use of micron sized nanoporous diatom algae exoskeletons for inhibitor storage and sustained corrosion protection of coated aluminium structures upon damage is presented. In this concept the algae exoskeleton allows local inhibitor loading, limits the interaction between the cerium and the epoxy/amine coating and allows for diffusion-controlled release of the inhibitor when needed. The inhibitor release and corrosion protection by loaded exoskeletons was evaluated by UV/Vis spectrometry, a home-built optical-electrochemical setup, and Raman spectroscopy. Although this concept has been proven for a cerium-epoxy-aluminium alloy system the main underlying principle can be extrapolated to other inhibitor-coating-metal systems.