Putting the RAFT in GRAFT

intermolecular graft exchange between bottlebrush polymers using reversible addition–fragmentation chain transfer

Journal Article (2022)
Author(s)

Satu Häkkinen (University of Warwick)

W.E. Dyer (University of Warwick)

Andrew Kerr (University of Warwick)

Sébastien Perrier (University of Warwick)

Affiliation
External organisation
DOI related publication
https://doi.org/10.1039/d1py01510a
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Publication Year
2022
Language
English
Affiliation
External organisation
Issue number
4
Volume number
13
Pages (from-to)
479-484

Abstract

A versatile synthetic methodology is presented for the preparation of graft copolymers with mixed graft distributions using reversible addition–fragmentation chain transfer (RAFT). The approach harnesses the ability of Z group-tethered grafts to fragment off the backbone to facilitate intermolecular graft exchange reactions between distinct starting materials.

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