Putting the RAFT in GRAFT

Häkkinen, Satu; Dyer, William E.; Kerr, Andrew; Perrier, Sébastien

Putting the RAFT in GRAFT

intermolecular graft exchange between bottlebrush polymers using reversible addition–fragmentation chain transfer

Journal article (2022)

Authors

Satu Häkkinen University of Warwick

William E. Dyer University of Warwick

Andrew Kerr University of Warwick

Sébastien Perrier University of Warwick

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Published Date

2022

Language

English

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Abstract

A versatile synthetic methodology is presented for the preparation of graft copolymers with mixed graft distributions using reversible addition–fragmentation chain transfer (RAFT). The approach harnesses the ability of Z group-tethered grafts to fragment off the backbone to facilitate intermolecular graft exchange reactions between distinct starting materials.

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