Putting the RAFT in GRAFT

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Putting the RAFT in GRAFT

intermolecular graft exchange between bottlebrush polymers using reversible addition–fragmentation chain transfer

Journal Article (2022)

Author(s)

Satu Häkkinen (University of Warwick)

W.E. Dyer (University of Warwick)

Andrew Kerr (University of Warwick)

Sébastien Perrier (University of Warwick)

Affiliation

External organisation

DOI related publication

https://doi.org/10.1039/d1py01510a Final published version

To reference this document use

https://resolver.tudelft.nl/uuid:56c3e0a1-6819-4762-9d74-875da7b87711

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Publication Year

2022

Language

English

Affiliation

External organisation

Issue number

4

Volume number

13

Pages (from-to)

479-484

Downloads counter

237

Abstract

A versatile synthetic methodology is presented for the preparation of graft copolymers with mixed graft distributions using reversible addition–fragmentation chain transfer (RAFT). The approach harnesses the ability of Z group-tethered grafts to fragment off the backbone to facilitate intermolecular graft exchange reactions between distinct starting materials.