Photoswitchable metal organic frameworks: turn on the lights and close the windows

Journal Article (2016)
Author(s)

Sonia Castellanos Ortega (TU Delft - Applied Sciences)

Freek Kapteijn (TU Delft - Applied Sciences)

Jorge Gascon (TU Delft - Applied Sciences)

Research Group
ChemE/Catalysis Engineering
DOI related publication
https://doi.org/10.1039/C5CE02543E Final published version
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Publication Year
2016
Language
English
Research Group
ChemE/Catalysis Engineering
Volume number
18
Pages (from-to)
4006-4012
Downloads counter
216
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Abstract

The ability of modulating the properties of metal–organic frameworks (MOF) on demand by external light-stimuli is a most appealing pathway to enhance their performance in storage and separation and to render novel advanced applications. Photoswitchable linkers of different nature have been inserted in several MOF structures either as integral parts of their scaffolds or as guests in the pores. In this highlight we analyse the different strategies and expose some aspects that should be considered in the design of new generations of photoswitchable MOFs