Base free transfer hydrogenation using a covalent triazine framework based catalyst
Anastasiya Bavykina (TU Delft - ChemE/Catalysis Engineering)
H.H. Mautscke (Universitat Politécnica de Valencia)
Michiel Makkee (TU Delft - ChemE/Catalysis Engineering)
Freek Kapteijn (TU Delft - ChemE/Catalysis Engineering)
Jorge Gascon (TU Delft - ChemE/Catalysis Engineering)
FX Llabres i Xamena (Universitat Politécnica de Valencia)
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Abstract
Isomerisation of allylic alcohols to saturated ketones can be efficiently catalysed by a heterogeneous molecular system resulting from IrIIICp* anchoring to a covalent triazine framework. The obtained catalysts are active, selective, and fully recyclable.
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