Curly malachite on archaeological bronze

A systematic study of the shape and phenomenological approach of its formation mechanism

Journal article (2016)

Authors

J. van der Stok-Nienhuis (OLD) MSE-4 , Cultural Heritage Agency of the Netherlands
Luc Robbiola Université de Toulouse
Roberta Giuliani University of Bologna
Ineke Joosten Cultural Heritage Agency of the Netherlands
Hans Huisman Cultural Heritage Agency of the Netherlands
Bertil van Os Cultural Heritage Agency of the Netherlands
J. Sietsma (OLD) MSE-3
Research Group
(OLD) MSE-4
Copyright: © 2016 J. van der Stok-Nienhuis, Luc Robbiola, Roberta Giuliani, Ineke Joosten, Hans Huisman, Bertil van Os, J. Sietsma
Morphology Corrosion Pseudomorph Nucleation and growth Curly malachite Archaeological bronze
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Published Date

2016

Language

English

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Research Group

(OLD) MSE-4

Abstract

Curly malachite (CM) is found as a green cupric carbonate hydroxide corrosion product on archaeological bronze, mostly on artefacts retrieved from graves. In this paper, a morphological characterization approach is proposed, enabling the investigation of the formation process of CM. It is suggested that curly malachite precipitates from an aqueous solution, for which the surrounding soil conditions provide local triggers. Anthropic activities associated with ritual burials do not significantly affect the growth of CM. It is also confirmed that curly malachite is usually not a pseudomorph of formerly organic material. Although the understanding of the formation process is far from complete, this study has shown that CM is expected to be found more often than is currently recognized, due to its relatively simple formation mechanisms and boundary conditions.