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Optimization of operational parameters in the mechanochemical regeneration of sodium borohydride (NaBH4)

Journal Article (2025)
Author(s)

Santiago Garrido Nuñez (TU Delft - Mechanical Engineering)

Dingena L. Schott (TU Delft - Mechanical Engineering)

Johan T. Padding (TU Delft - Mechanical Engineering)

Research Group
Complex Fluid Processing
DOI related publication
https://doi.org/10.1016/j.ijhydene.2024.11.360 Final published version
More Info
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Publication Year
2025
Language
English
Research Group
Complex Fluid Processing
Volume number
97
Pages (from-to)
640-648
Downloads counter
346
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Abstract

In this study we investigate the mechanochemical regeneration of sodium borohydride (NaBH4) from a system comprising hydrated sodium metaborate ( [Formula presented] ) and magnesium hydride (MgH2). We explore the individual and joint impact of key operational parameters (rotational speed, milling time, ball-to-powder ratio (BPR), and molar ratio) on the regeneration yield. Furthermore, a method for quantifying chemical conversion is introduced relying only on water and thus, offering environmental benefits. This approach additionally facilitates the production and storage of a “ready-to-use” NaBH4 solution with minimal losses at room temperature. Notably, a yield of 90% is achieved, with a 20% reduction in rotational speed compared to prior literature. This research contributes to sustainable hydrogen storage and presents practical advancements in mechanochemical processes.