Enhanced Optical Performance of BaMgAl10O17

Eu2+ Phosphor by a Novel Method of Carbon Coating

Journal Article (2016)
Research Group
ChemE/Product and Process Engineering
Copyright
© 2016 L.J. Yin, Juntao Dong, Yinping Wang, Bi Zhang, Zheng Yang Zhou, Xian Jian, Mengqiang Wu, Xin Xu, J.R. van Ommen, H.T.J.M. Hintzen
DOI related publication
https://doi.org/10.1021/acs.jpcc.5b10215
More Info
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Publication Year
2016
Language
English
Copyright
© 2016 L.J. Yin, Juntao Dong, Yinping Wang, Bi Zhang, Zheng Yang Zhou, Xian Jian, Mengqiang Wu, Xin Xu, J.R. van Ommen, H.T.J.M. Hintzen
Research Group
ChemE/Product and Process Engineering
Issue number
4
Volume number
120
Pages (from-to)
2355-2361
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Abstract

Many strategies have been adopted to improve thermal degradation of phosphors. Because of the stability and high transmittance of graphene, here we report a novel method of carbon coating on BaMgAl10O17:Eu2+ (BAM) phosphor particles through chemical vapor deposition. The chemical composition, microstructure, and luminescence performance of carbon-coated BAM were characterized carefully. This coating can be controlled within 3-10 atomic layers, depending on the reaction time. Because of the decrease of surface defects and the effective weakening effect of oxidizing Eu2+ to Eu3+ after carbon coating, different layer numbers showed an obvious effect on the optical properties of carbon-coated BAM. Carbon-coated BAM phosphors had higher emission intensity and better oxidation resistance at high temperature than uncoated BAM phosphors. These results indicate that the method of carbon coating on phosphor particles is a promising way to improve the luminescence properties of other phosphors used in lighting and display devices.

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