High-silica zeolites for adsorption of organic micro-pollutants in water treatment
A review
Nan Jiang (TU Delft - Sanitary Engineering)
R. Shang (TU Delft - Sanitary Engineering)
Sebastian G.J. Heijman (TU Delft - Sanitary Engineering)
Luuk Rietveld (TU Delft - Sanitary Engineering)
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Abstract
High-silica zeolites have been found to be effective adsorbents for the removal of organic micro-pollutants (OMPs) from impaired water, including various pharmaceuticals, personal care products, industrial chemicals, etc. In this review, the properties and fundamentals of high-silica zeolites are summarised. Recent research on mechanisms and efficiencies of OMP adsorption by high-silica zeolites are reviewed to assess the potential opportunities and challenges for the application of high-silica zeolites for OMP adsorption in water treatment. It is concluded that the adsorption capacities are well-related to surface hydrophobicity/hydrophilicity and structural features, e.g. micropore volume and pore size of high-silica zeolites, as well as the properties of OMPs. By using high-silica zeolites, the undesired competitive adsorption of background organic matter (BOM) in natural water could potentially be prevented. In addition, oxidative regeneration could be applied on-site to restore the adsorption capacity of zeolites for OMPs and prevent the toxic residues from re-entering the environment.