Mg-Ti-H thin films as switchable solar absorbers

Journal Article (2008)
Author(s)

A. Baldi (Vrije Universiteit Amsterdam)

D. M. Borsa (Vrije Universiteit Amsterdam)

H. Schreuders (Vrije Universiteit Amsterdam)

J. H. Rector (Vrije Universiteit Amsterdam)

T. Atmakidis (Technische Uni­ver­si­tät Dort­mund)

M. Bakker (ECN Solar Energy)

H. A. Zondag (ECN Solar Energy)

W. G.J. van Helden (ECN Solar Energy)

B. Dam (Vrije Universiteit Amsterdam)

R. Griessen (Vrije Universiteit Amsterdam)

Affiliation
External organisation
DOI related publication
https://doi.org/10.1016/j.ijhydene.2008.01.026 Final published version
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Publication Year
2008
Language
English
Affiliation
External organisation
Journal title
International Journal of Hydrogen Energy
Issue number
12
Volume number
33
Pages (from-to)
3188-3192
Downloads counter
152

Abstract

The reflection and transmission spectra of Pd capped Mgy Ti1 - y thin films (y = 0.7, 0.8 and 0.9) are measured in the 0.5-5.5 eV energy range, both in the as-prepared and hydrogenated states. Upon hydrogenation these films switch reversibly from a shiny metallic state into a "black" absorbing one. The composition and thicknesses can be tailored to achieve high solar absorptance and low thermal emittance in the hydrogenated state. The combination of these two characteristics is interesting for the application of this material as switchable absorber in solar collectors. The use of a Mgy Ti1 - y switchable absorber in solar collectors allows to lower the stagnation temperature from 180 to 80 °C. The collector efficiency is affected only minimally.