Solid-state molecular nanomagnet inclusion into a magnetic metal-organic framework: interplay of the magnetic properties

Journal article (2016)

Authors

M Mon Universitat de València

A Pascual-Alvarez Universitat de València

TM Grancha Universitat de València

J Cano Universitat de València

J Ferrando-Soria Universitat de València

F Lloret Universitat de València

J. Gascon Sabate

J Pasan Universidad de La Laguna, La Laguna

D Armentano University of Calabria

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Published Date

2016

Language

English

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Abstract

Single-ion magnets (SIMs) are the smallest possible magnetic devices and are a controllable, bottom-up approach to nanoscale magnetism with potential applications in quantum computing and high-density information storage. In this work, we take advantage of the promising, but yet insufficiently explored, solid-state chemistry of metal–organic
frameworks (MOFs) to report the single-crystal to single-crystal inclusion of such molecular nanomagnets within the pores of a magnetic MOF. The resulting host– guest supramolecular aggregate is used as a playground in the first in-depth study on the interplay between the internal magnetic field created by the long-range magnetic ordering
of the structured MOF and the slow magnetic relaxationof the SIM