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Photoenzymatic epoxidation of styrenes

Journal Article (2019)
Author(s)

M.M.C.H. Van Schie (TU Delft - BT/Biocatalysis)

Caroline Paul (Wageningen University & Research)

Isabel W.C.E. Arends (Universiteit Utrecht)

F. Hollmann (TU Delft - BT/Biocatalysis)

Research Group
BT/Biocatalysis
Copyright
© 2019 M.M.C.H. van Schie, C.E. Paul, I.W.C.E. Arends, F. Hollmann
DOI related publication
https://doi.org/10.1039/c8cc08149b
More Info
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Publication Year
2019
Language
English
Copyright
© 2019 M.M.C.H. van Schie, C.E. Paul, I.W.C.E. Arends, F. Hollmann
Research Group
BT/Biocatalysis
Issue number
12
Volume number
55
Pages (from-to)
1790-1792
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Abstract


Two-component-diffusible-flavomonooxygenases are versatile biocatalysts for selective epoxidation-, hydroxylation- or halogenation reactions. Their complicated molecular architecture can be simplified using photochemical regeneration of the catalytically active, reduced FADH
2
prosthetic group. In this contribution we provide the proof-of-concept and characterization for the direct regeneration of the styrene monooxygenase from Pseudomonas.