Safeguarding Water Quality
HPLC-DAD as Early Warning System
Nienke Meekel (Vrije Universiteit Amsterdam, KWR Water Research Institute)
Marijke W. de Bar (Ministerie van Infrastructuur en Waterstaat)
Erik Emke (KWR Water Research Institute)
Martijn M. Pijnappels (Ministerie van Infrastructuur en Waterstaat)
Runa Kooper-Mookerji (Aqualab Zuid)
Peter van Diepenbeek (Waterleiding Maatschappij Limburg)
Astrid Fischer (TU Delft - Sanitary Engineering, Evides Waterbedrijf)
René van Doorn (KWR Water Research Institute)
Asmaïl Asgadaouan (KWR Water Research Institute)
Patrick S. Bäuerlein (KWR Water Research Institute)
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Abstract
Harmonized online solid phase extraction (SPE) coupled to high-performance liquid chromatography (HPLC) with diode array detection (DAD) has proven its suitability as a robust early warning system for water quality in The Netherlands. A retention index (KRetI), validated through interlaboratory ring trials, together with a shared UV spectral database, facilitates data comparability across laboratories. The technique enables early detection of trends and incidental contamination, triggering alarm systems, and allowing for measures to be taken to protect the drinking water supply and the river’s ecosystem.
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