Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis
S. Sachdeva (TU Delft - OLD ChemE/Organic Materials and Interfaces)
A. Pustovarenko (TU Delft - ChemE/Catalysis Engineering)
Ernst J. R. Sudhölter (TU Delft - OLD ChemE/Organic Materials and Interfaces)
F. Kapteijn (TU Delft - ChemE/Catalysis Engineering)
Louis de Smet (TU Delft - OLD ChemE/Organic Materials and Interfaces)
Jorge Gascon Sabate (TU Delft - ChemE/Catalysis Engineering)
More Info
expand_more
Other than for strictly personal use, it is not permitted to download, forward or distribute the text or part of it, without the consent of the author(s) and/or copyright holder(s), unless the work is under an open content license such as Creative Commons.
Abstract
A study of a copper-based metal–organic framework (MOF) synthesized by an electrochemical route is presented. Morphological and adsorption properties of the MOF synthesized as bulk powder and on supported copper surfaces were investigated. Differences in these properties and structural refinement studies indicate that when 4,4′,4′′-s-triazine-2,4,6-triyl-tribenzoic acid (H3TATB) is used as linker interpenetration can be prevented when the structure is grown on a surface.
Graphical abstract: Control of interpenetration of copper-based MOFs on supported surfaces by electrochemical synthesis
help_outline