Laser induced predissociation of SF6 clusters

Journal Article (1981)
Author(s)

JMP Geraedts (Radboud Universiteit Nijmegen, Fysisch Laboratorium)

S. Setiadi (Radboud Universiteit Nijmegen)

S. Stolte (Radboud Universiteit Nijmegen)

J. Reuss (Radboud Universiteit Nijmegen)

Affiliation
External organisation
DOI related publication
https://doi.org/10.1016/0009-2614(81)80016-4
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Publication Year
1981
Language
English
Affiliation
External organisation
Issue number
2
Volume number
78
Pages (from-to)
277-282

Abstract

Dimer predissociation is sensitively detected as attenuation of the SF+5 ion signal from a SF6 molecular beam crossed by a line tunable cw CO2 laser. The dimer spectra show a double peak structure which is assigned to the symmetric and anti-symmetric combination of the v3 vibration. The minimum observed linewidth is 3 cm-1 fwhm.

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