Radical induced Cationic Frontal Polymerization as a Versatile Tool for Epoxy Curing and Composite Production

Journal Article (2016)
Author(s)

Daniel Bomze (Technische Universität Wien)

Patrick Knaack (Technische Universität Wien)

Thomas Koch (Technische Universität Wien)

H Jin (TU Delft - DC systems, Energy conversion & Storage)

Robert Liska (Technische Universität Wien)

Research Group
DC systems, Energy conversion & Storage
DOI related publication
https://doi.org/10.1002/pola.28274
More Info
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Publication Year
2016
Language
English
Research Group
DC systems, Energy conversion & Storage
Issue number
23
Volume number
54
Pages (from-to)
3751-3759

Abstract

Radical induced cationic frontal polymerization (RICFP) is an extremely powerful and elegant alternative curing technique that allows cationic bulk curing of epoxy resins with very little energy consumption, as well as curing in compart-
ments that are not readily accessible. We recently introduced a bisphenol-A diglycidylether (BADGE) based system that allows the bubble-free photocuring of this widely used epoxy resin. In this article, we describe the high storage stability and possibili-ties to influence the curing speed via the initiator concentra-
tions of different formulations. These properties allow the adjustment of the frontal polymerization to ones need. We also show that the (thermo)mechanical and electrical properties of frontal cured epoxy polymers compares favorably with those of state of the art material. Finally, different strategies to over-
come the challenges on producing epoxy resin based mica
composites via RICFP are presented.

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