Fouling and chemical stability study on SiC-Al2O3 ultrafiltration membrane for sodium alginate filtration under constant flux crossflow mode

Abstract

Trials of surface modifications using low pressure chemical vapor deposition (LPCVD) has successfully decreased the high temperature needed for the fabrication of SiC membrane from 2000°C to below 900 °C. With this great success on the reduction of the energy con-sumption, however, further studies on the chemical stability and the fouling features of this kind of membrane were necessary. In this research, experiments were done on the SiC-Al2O3 UF membrane fabricated by LPCVD to study its chemical stability in a NaClO solution and its fouling features when filtrating sodium alginate and surface water under constant flux cross-flow mode. The backwash efficiency and the fouling resistance were analysed as well to further elucidate the fouling composition.
According to the results, the SiC-Al2O3 membrane coated under higher temperature (860°C) remained stable in the NaClO solution for 200 h, (1% for 100 h and then 5% for 100 h) while the membrane coated under lower temperature (750°C) showed a water permeability increase during chlorine treatment, indicating the dissolution of the SiC layer. The high temperature coated membrane (860°C) had a better antifouling ability than low temperature coated mem-brane (750°C) and the pristine membrane especially when filtrating the pure sodium alginate (SA) solution without Ca2+ under normal flux (170 LMH) or the surface water under lower flux (65 LMH). Cake filtration was observed in the fouling curves when the critical flux was not exceeded. The addition of Ca2+ into the pure SA solution resulted in the decrease of elec-trical repulsion and the increase of bridging between foulants and membrane surface. These led to the severe fouling of the high temperature coated membrane. The low temperature coated membrane had better antifouling ability than high temperature coated membrane and the pristine membrane when 2 mmol/L of Ca2+ was added. However, the backwash (back-wash flux of around 340 LMH for normal flux condition and around 195 LMH for lower flux condition) was not efficient for all the membranes and should be improved in the future ex-periments.