Syngas production via microwave-assisted dry reforming of methane
Ignacio de Dios García (Student TU Delft)
Andrzej Stankiewicz (TU Delft - Intensified Reaction and Separation Systems)
H. Nigar (TU Delft - Complex Fluid Processing)
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Abstract
Energy-efficient CH4-CO2 valorization to fuels and chemicals presents an urgent need considering the great variety of methane sources and the removal of greenhouse gases. In the present work, the microwave-assisted dry reforming of methane, DRM, has been carried out in a custom-designed rectangular mono-mode microwave applicator over several catalyst-support combinations, i.e., Pt/C, Ni/Al2O3, mechanical mixture of Ni/Al2O3-SiC and Ni/SiC. The high and steady conversions of CH4 and CO2 were obtained in the case of the mechanical mixture of Ni/Al2O3-SiC and Ni/SiC. In all the combinations investigated, the conversions reached up to 90% at a WHSV of 11,000 mL/g/h, and microwave power input of 45–60 W, at 800 °C. No significant catalyst deactivation has been observed during the 6-h operation except of Pt/C catalyst. Moreover, the microwave-assisted dry reforming of methane over Ni/SiC was shown to be an interesting, cheap process candidate, able to compete with the steam reforming.
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