Strategies for the Direct Catalytic Valorization of Methane Using Heterogeneous Catalysis

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Strategies for the Direct Catalytic Valorization of Methane Using Heterogeneous Catalysis

Challenges and Opportunities

Journal Article (2016)

Author(s)

Alma I. Olivos-Suarez (TU Delft - ChemE/Catalysis Engineering)

A. Szecsenyi (Eindhoven University of Technology, TU Delft - ChemE/Catalysis Engineering)

Emiel J M Hensen (Eindhoven University of Technology)

Javier Ruiz-Martinez (AkzoNobel, Universiteit Utrecht)

Evgeny A. Pidko (Eindhoven University of Technology)

J. Gascon (TU Delft - ChemE/Catalysis Engineering)

Heterogeneous catalysis Reaction mechanism Alkane functionalization C-H bond activation Methane activation Methane valorization Radical rebound mechanism

DOI related publication

https://doi.org/10.1021/acscatal.6b00428 Final published version

To reference this document use

https://resolver.tudelft.nl/uuid:fe9d401d-19e3-4818-a80e-3d5e80da4ec0

More Info

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Publication Year

2016

Language

English

Journal title

ACS Catalysis

Issue number

5

Volume number

6

Pages (from-to)

2965-2981

Downloads counter

264

Abstract

In this Perspective, we highlight the main challenges to be addressed in the development of heterogeneous catalysts for the direct functionalization of methane. Along with our personal view on current developments in this field, we outline the main mechanistic, engineering, and catalyst design issues that have hampered implementation of new technologies and highlight possible paths to overcome these problems.