VUV-UV-vis photoluminescence, X-ray radioluminescence and energy transfer dynamics of Ce3+ and Eu2+ in Sr2MgSi2O7

Title

VUV-UV-vis photoluminescence, X-ray radioluminescence and energy transfer dynamics of Ce3+ and Eu2+ in Sr2MgSi2O7

 Author

Wen, Donghao (Sun Yat-sen University)
Li, Quanfeng (Sun Yat-sen University)
Ou, Yiyi (Sun Yat-sen University)
Yang, Yunlin (Sun Yat-sen University)
Qi, Zeming (University of Science and Technology of China)
Dorenbos, P. (TU Delft RST/Luminescence Materials) ORCID 0000-0002-1004-8353
Liang, Hongbin (Sun Yat-sen University)

Date

2022

 Abstract

Ce3+ and Eu2+ doped and Ce3+-Eu2+ co-doped Sr2MgSi2O7 phosphors are prepared via a high-temperature solid-state reaction technique. The synchrotron radiation vacuum ultraviolet-ultraviolet (VUV-UV) excitation and ultraviolet-visible (UV-vis) emission spectra of diluted Ce3+ and Eu2+ doped Sr2MgSi2O7 samples are measured at cryogenic temperatures. The electron-vibrational interaction (EVI) between Ce3+ and its surroundings is analyzed. The dependencies of the 4f-5d transitions of Ce3+ on the structure of the host compounds Sr2MgSi2O7, Ba2MgSi2O7 and BaMg2Si2O7 are discussed in detail. Then the thermal quenching channel is proposed based on the measurements of temperature dependent luminescence intensities and decay times of Ce3+ and Eu2+ in Sr2MgSi2O7, and the Ce3+ → Eu2+ energy transfer mechanism is understood by three luminescence dynamic models. In addition, Sr2MgSi2O7:Ce3+/Eu2+ samples are evaluated for the possibilities of X-ray detection applications using X-ray excited luminescence (XEL) spectroscopy, and it was found that they are not suitable.


 To reference this document use:

http://resolver.tudelft.nl/uuid:b36101d9-816f-4eed-a79d-d47113b7f1b6

 DOI

https://doi.org/10.1039/d2dt03165e

 Embargo date

2023-07-01

 ISSN

1477-9226

 Source

Dalton Transactions: the international journal for inorganic, organometallic and bioinorganic chemistry, 51 (46), 17809-17819

 Bibliographical note

Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public.

 Part of collection

Institutional Repository

 Document type

journal article

 Rights

© 2022 Donghao Wen, Quanfeng Li, Yiyi Ou, Yunlin Yang, Zeming Qi, P. Dorenbos, Hongbin Liang
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