Print Email Facebook Twitter From Lab to Market: Evaluating Performance Metrics for Electrochemical Ammonia Synthesis versus Haber-Bosch Title From Lab to Market: Evaluating Performance Metrics for Electrochemical Ammonia Synthesis versus Haber-Bosch Author Vlierboom, Alexander (TU Delft Electrical Engineering, Mathematics and Computer Science; TU Delft Applied Sciences) Contributor Kortlever, R. (mentor) de Jong, W. (mentor) Izelaar, B. (mentor) Ramdin, M. (mentor) Pérez-Fortes, Mar (mentor) Degree granting institution Delft University of Technology Programme Electrical Engineering | Sustainable Energy Technology Date 2023-05-15 Abstract Ammonia (NH3) is a bulk commodity chemical known for its large production volumes and application in the global fertiliser industry, and is more recently being explored for its role as a sustainable energy vector. The industry standard ammonia production method is the century-old Haber-Bosch (HB) process, which is power by fossil fuels, and is accompanied with high energy intensity and large carbon-dioxide emissions. In this research, conceptual processes for the electrochemical synthesis of ammonia via the direct electrochemical nitrogen reduction reaction (e-NRR) from air and water were developed to assess their technical and economic viability compared to the HB benchmark. Different scales (91, 544 and 2055 t d-1) and electrolyzer cell configurations (alkaline electrolyzer (AEL), gas-diffusion electrode flow cell (GDE) and solid oxide electrolyzer (SOEL)) were considered. The results showed that small-scale production is more feasible for e-NRR NH3 synthesis due to the economies of scale of the HB benchmark. Among different electrolyzer types, the gas-diffusion electrode flow cell was found to be the most practical and economical for e-NRR NH3 synthesis. A sensitivity analysis showed that the electricity price is the most important parameter for the feasibility of e-NRR, and should ideally be as low as possible. Performance parameters of the electrolyzer, such as stack cost, operational current density, and faradaic efficiency, were optimized for minimal NH3 production cost, but were challenging to estimate due to the early stage of e-NRR technology. An optimized case was presented that demonstrated e-NRR NH3 can reach HB-parity, but the validity of the optimised parameters was difficult. It is advised that reliable laboratory-scale demonstrations are needed for an accurate assessment of the commercial feasibility of electrochemical NH3 synthesis. Subject electrochemical nitrogen reduction reactionammonia, techno-economic analysisconceptual process designenergy analysis To reference this document use: http://resolver.tudelft.nl/uuid:dc887fb6-7365-43cb-9eca-0ea09b791f1e Part of collection Student theses Document type master thesis Rights © 2023 Alexander Vlierboom Files PDF Msc_Thesis_Alexander_Vlie ... rsion_.pdf 4.22 MB Close viewer /islandora/object/uuid:dc887fb6-7365-43cb-9eca-0ea09b791f1e/datastream/OBJ/view