Print Email Facebook Twitter Leaching behaviour of a crystallisation inhibitor in mortars Title Leaching behaviour of a crystallisation inhibitor in mortars Author Kamat, Ameya (TU Delft Heritage & Architecture) Lubelli, B. (TU Delft Heritage & Architecture) Schlangen, E. (TU Delft Materials and Environment) Date 2023 Abstract This paper investigates the leaching behaviour of sodium ferrocyanide, a known crystallisation inhibitor of sodium chloride, which is added to mortars for mitigation of salt decay. Leaching and depletion of the inhibitor is a practical performance related issue that might over time, make the inhibitor less effective against salt decay. In this research, the inhibitor was added to natural hydraulic lime (NHL) mortars during the mixing stage. Leaching of the inhibitor from the hardened mortar was assessed experimentally in laboratory. Both diffusion- and advection-driven transport mechanisms were considered. Diffusion experiments were carried out in a tank leaching test setup. Capillary absorption and drying cycles were used as a driving force to study advection-driven transport. Quantification of the leached species was carried out using various analytical techniques, including UV-VIS spectroscopy, ICP-OES and ion chromatography. The results from the tank leaching test show a high effective diffusion coefficient of ferrocyanide ions, in the same order of magnitude as sodium chloride transport. The advection test shows accumulation of the inhibitor at the evaporative surface and depletion of the inhibitor in the inner layers with successive wet-dry cycles. Based on these results it can be inferred that the degree of inhibitor leaching is significant and needs to be minimised to prolong the positive effect of the inhibitor on mortar durability. Potential solutions to reduce inhibitor leaching are discussed. Subject AdvectionCrystallisation inhibitorDiffusionLeachingNatural hydraulic lime mortarSalt damageSodium chlorideSodium ferrocyanide To reference this document use: http://resolver.tudelft.nl/uuid:ea432d55-fbed-4d2e-8274-2764c926bbb9 DOI https://doi.org/10.1016/j.jobe.2023.107933 ISSN 2352-7102 Source Journal of Building Engineering, 79 Part of collection Institutional Repository Document type journal article Rights © 2023 Ameya Kamat, B. Lubelli, E. Schlangen Files PDF 1_s2.0_S2352710223021137_main.pdf 7.03 MB Close viewer /islandora/object/uuid:ea432d55-fbed-4d2e-8274-2764c926bbb9/datastream/OBJ/view