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Shan, M. (author), Liu, X. (author), Wang, X. (author), Liu, Z. (author), Iziyi, H. (author), Ganapathy, S. (author), Gascon, Jorge (author), Kapteijn, F. (author)Membranes with high selectivity and permeance are needed to reduce energy consumption in hydrogen purification and pre-combustion CO <sub>2</sub> capture. Polybenzimidazole (PBI) is one of the leading membrane materials for this separation. In this study, we present superior novel supported PBI (poly(p-phenylene benzobisimidazole), PBDI)...journal article 2019
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Liu, X. (author), Wang, X. (author), Bavykina, A.V. (author), Chu, L. (author), Shan, M. (author), Sabetghadam, Anahid (author), Miro, H. (author), Kapteijn, F. (author), Gascon, Jorge (author)The preparation and the performance of mixed matrix membranes based on metal-organic polyhedra (MOPs) are reported. MOP fillers can be dispersed as discrete molecular units (average 9 nm in diameter) when low filler cargos are used. In spite of the low doping amount (1.6 wt %), a large performance enhancement in permeability, aging resistance...journal article 2018
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Shan, M. (author), Liu, X. (author), Wang, X. (author), Yarulina, I. (author), Seoane, Beatriz (author), Kapteijn, F. (author), Gascon, Jorge (author)The development of new membranes with high H<sub>2</sub> separation performance under industrially relevant conditions (high temperatures and pressures) is of primary importance. For instance, these membranes may facilitate the implementation of energy-efficient precombustion CO<sub>2</sub> capture or reduce energy intensity in other...journal article 2018
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Shan, M. (author), Seoane, Beatriz (author), Pustovarenko, Alexey (author), Wang, X. (author), Liu, X. (author), Yarulina, I. (author), Abou-Hamad, Edy (author), Kapteijn, F. (author), Gascon, Jorge (author)The performance of mixed-matrix membranes (MMMs) based on Matrimid<sup>®</sup> and benzimidazole-linked polymers (BILPs) have been investigated for the separation CO<sub>2</sub>/N<sub>2</sub> and the dependency on the filler porosity. BILPs with two different porosities (BILP-101 and RT-BILP-101) were synthesized through controlling the...journal article 2018