Peroxygenase-Catalysed Sulfoxidations in Non-Aqueous Media

Chiral sulfoxides are valuable building blocks in asymmetric synthesis. However, the biocatalytic synthesis of chiral sulfoxides is still challenged by low product titres. Herein, we report the use of peroxygenase as a catalyst for asymmetric sulfoxidation under non-aqueous conditions. Upon covalent immobilisation, the peroxygenase showed...

Laser shape variation influence on melt pool dynamics and solidification microstructure in laser powder bed fusion

The shape variation of the laser beam is evidently observed in the laser powder bed fusion (LPBF) process because of changes in laser incidence angle and misalignment between the build plate and the laser focus plane. This issue is particularly relevant in large-scale LPBF systems where the laser beam needs to scan a large build area. However...

Degradation behaviors and in-vivo biocompatibility of a rare earth- and aluminum-free magnesium-based stent

Biodegradable stents can provide scaffolding and anti-restenosis benefits in the short term and then gradually disappear over time to free the vessel, among which the Mg-based biodegradable metal stents have been prosperously developed. In the present study, a Mg-8.5Li (wt.%) alloy (RE- and Al-free) with high ductility (> 40%) was...

A Highly Linear Wideband Polar Class-E CMOS Digital Doherty Power Amplifier

This article presents the first application of a digital-intensive intrinsically linear digitally controlled class-E technique in a Doherty configuration. By careful nonlinear segmentation and multiphase RF-clocking along with overdrive-voltage control and automatic duty-cycle correction, it is shown that even the nonlinearities related to...

Video Captioning by Adversarial LSTM

In this paper, we propose a novel approach to video captioning based on adversarial learning and long short-term memory (LSTM). With this solution concept, we aim at compensating for the deficiencies of LSTM-based video captioning methods that generally show potential to effectively handle temporal nature of video data when generating...