Unravelling the corrosion protection mechanism of silyl ester by combined electrochemistry and x-ray computed tomography

Recently, encapsulated silyl esters have been shown to act as efficient healing agents for self-healing anticorrosive coatings. While the positive protective effects were irrefutable, the actual protection mechanism has not been clarified yet. In this study, x-ray computed ?-tomography and electrochemical impedance spectroscopy have been...

Unravelling the corrosion protection mechanism of silyl ester by combined electrochemistry and x-ray computed tomography

Recently, encapsulated silyl esters have been shown to act as efficient healing agents for self-healing anticorrosive coatings. While the positive protective effects were irrefutable, the actual protection mechanism has not been clarified yet. In this study, x-ray computed ?-tomography and electrochemical impedance spectroscopy have been...

Simultaneous optical and electrochemical monitoring of the protective effect of functional surface healing agents

Encapsulation of reactive agents embedded within a matrix is the most studied concept to develop self-healing materials. The most common approaches employ either a single component with catalyst dispersed in the matrix or a single environment-reactive component for corrosion protection [1]. Recently an approach for corrosion protection based on...

Model based design of self-healing expandable coatings under different environmental conditions

A long-lasting barrier protection at damaged sites of coated system can be achieved by means of an active response of the primer. This may be attained through the release of reactive liquids from dispersed containers, the increase of the local mobility of the polymeric network, or the expansion of (dispersed elements in) the primer [1]. Such...

Model based design of self-healing expandable coatings under different environmental conditions

A long-lasting barrier protection at damaged sites of coated system can be achieved by means of an active response of the primer. This may be attained through the release of reactive liquids from dispersed containers, the increase of the local mobility of the polymeric network, or the expansion of (dispersed elements in) the primer [1]. Such...

Self-healing anticorrosive organic coating based on the release of a reactive silyl ester: Use of local electrochemical techniques (poster abstract)

A mechanical model for the self healing response of coatings based on expansive phases (abstract)