Selectivity control between reverse water-gas shift and fischer-tropsch synthesis in carbon-supported iron-based catalysts for CO₂ hydrogenation

CO₂ hydrogenation to chemicals and fuels has the potential to alleviate CO₂ emissions and displace fossil resources simultaneously via consecutive RWGS and FTS reactions, also known as CO₂-FTS. As Fe-based catalysts are active and selective for both reactions, their bifunctionality requires a delicate balance...

Modelling of material removal due to sliding wear caused by bulk material

A convex pattern surface has been proposed and optimized to reduce sliding wear of bulk handling equipment by adjusting the flow behaviour of bulk material. This study aims at modelling the surface deformation of the convex pattern sample to investigate how effectively the sample reduces sliding wear. Archard wear model and a deformable...

Unveiling the Structure Sensitivity for Direct Conversion of Syngas to C2-Oxygenates with a Multicomponent-Promoted Rh Catalyst

Abstract: Mn and Li promoted Rh catalysts supported on SiO₂ with a thin TiO₂ layer were synthesized by stepwise incipient wetness impregnation approach. The thin TiO₂ layer on the surface of SiO₂ was proved to stabilize those small Rh nanoparticles and hinder their agglomeration. The reducibility of...

Effect of pore size distribution and particle size of porous metal oxides on phosphate adsorption capacity and kinetics

Phosphate is a vital nutrient but its presence in surface waters even at very low concentrations can lead to eutrophication. Adsorption is often suggested as a step for reducing phosphate down to very low concentrations. Porous metal oxides can be used as granular adsorbents that have a high surface area and hence a high adsorption capacity....