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Bannenberg, L.J. (author), Verhoeff, D. (author), Jonckers Newton, Nick (author), Thijs, M.A. (author), Schreuders, H. (author)
Here, we study the structural and optical properties of tetragonal β-tantalum-sputtered thin films both ex situ and when exposed to hydrogen, with a focus on optical hydrogen sensing applications. Using optical transmission measurements, out-of-plane and in-plane X-ray diffraction, and X-ray and neutron reflectometry, we show that thin film β...
journal article 2024
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Wu, Z. (author), De Wit, Lidwin (author), Beek, Melanie (author), Colombi, G. (author), Chaykina, D. (author), Schreuders, H. (author), Schut, H. (author), Butterling, Maik (author), Brück, E.H. (author), Dam, B. (author), Eijt, S.W.H. (author)
Cycling stability of the photochromic effect in rare-earth oxyhydride thin films is of great importance for long-term applications such as smart windows. However, an increasingly slower bleaching rate upon photochromic cycling was found in yttrium oxyhydride thin films; the origin of this memory effect is yet unclear. In this work, the...
journal article 2024
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Colombi, G. (author), Boshuizen, B. (author), Chaykina, D. (author), Hsu, Y. (author), Schreuders, H. (author), Savenije, T.J. (author), Dam, B. (author)
At ambient conditions, rare-earth oxyhydride thin films show reversible photochromism and photoconductivity, while their mechanism and relation are still unclear. In this work, this question is explored with in situ time-resolved measurements of both optical and transport properties of Gd-based oxyhydride thin films. It is found that p-type...
journal article 2023
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Chaykina, D. (author), Colombi, G. (author), Schreuders, H. (author), Dam, B. (author)
Photochromism has been reported for several rare-earth (RE) metal oxyhydride thin films and is characterized by a reversible darkening of the sample when exposed to light with energy greater than its optical bandgap. Here, we extend the range of known photochromic RE-oxyhydrides to include samarium oxyhydrides. These SmH3−2xOx thin films are...
journal article 2023
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Bannenberg, L.J. (author), Schreuders, H. (author), van Beugen, N. (author), Kinane, Christy (author), Hall, Stephen (author), Dam, B. (author)
Accurate, cost-efficient, and safe hydrogen sensors will play a key role in the future hydrogen economy. Optical hydrogen sensors based on metal hydrides are attractive owing to their small size and costs and the fact that they are intrinsically safe. These sensors rely on suitable sensing materials, of which the optical properties change...
journal article 2023
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Ripepi, D. (author), Schreuders, H. (author), Mulder, F.M. (author)
Ammonia is an indispensable commodity and a potential carbon free energy carrier. The use of H permeable electrodes to synthesize ammonia from N <sub>2</sub>, water and electricity, provides a promising alternative to the fossil fuel based Haber-Bosch process. Here, H permeable Ni electrodes are investigated in the operating temperature range...
journal article 2023
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Bannenberg, L.J. (author), Blom, Larissa (author), Sakaki, Kouji (author), Asano, Kohta (author), Schreuders, H. (author)
Nanostructured metal hydrides could play a key role in a hydrogen economy. The nanostructuring or confinement of these materials as, e.g., thin films significantly affects the structural and functional properties. For tantalum hydride, a versatile hydrogen sensing material, we show that the confinement of tantalum as a thin film extends the...
journal article 2023
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Chaykina, D. (author), Usman, I.N. (author), Colombi, G. (author), Schreuders, H. (author), Tyburska-Pueschel, Beata (author), Wu, Z. (author), Eijt, S.W.H. (author), Bannenberg, L.J. (author), De Wijs, Gilles A. (author), Dam, B. (author)
To develop an understanding of the photochromic effect in rare-earth metal oxyhydride thin films (REH3-2xOx, here RE = Y), we explore the aliovalent doping of the RE cation. We prepared Ca-doped yttrium oxyhydride thin films ((CazY1-z)HxOy) by reactive magnetron cosputtering with Ca doping concentrations between 0 and 36 at. %. All of the...
journal article 2022
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Chaykina, D. (author), Usman, I.N. (author), Colombi, G. (author), Schreuders, H. (author), Tyburska-Pueschel, Beata (author), Wu, Z. (author), Eijt, S.W.H. (author), Bannenberg, L.J. (author), De Wijs, Gilles A. (author), Dam, B. (author)
The energy axes of the RBS and ERD data (contained in Figures 2a,b,d,e, and S4) were originally underestimated, and the corrected figures appear below and in the Supporting Information. The change is in the conversion from raw data to the energy scale, which was initially converted incorrectly. The rescaled x-axis does not change the data...
journal article 2022
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Kolen, M. (author), Antoniadis, Grigorios (author), Schreuders, H. (author), Boshuizen, B. (author), van Noordenne, D.D. (author), Ripepi, D. (author), Smith, W.A. (author), Mulder, F.M. (author)
The electrochemical nitrogen reduction reaction (NRR) is a promising alternative to the current greenhouse gas emission intensive process to produce ammonia (NH<sub>3</sub>) from nitrogen (N<sub>2</sub>). However, finding an electrocatalyst that promotes NRR over the competing hydrogen evolution reaction (HER) has proven to be difficult. This...
journal article 2022
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Chaykina, D. (author), De Krom, T. (author), Colombi, G. (author), Schreuders, H. (author), Suter, A. (author), Prokscha, T. (author), Dam, B. (author), Eijt, S.W.H. (author)
Thin films of rare-earth metal oxyhydrides, such as yttrium oxyhydrides (YH3-2xOx), show a photochromic effect where the transparency of the films decreases reversibly upon exposure to UV light. However, the exact mechanism behind this effect is unknown. In this paper, we describe the behavior of YH3-2xOx thin films, with different O2-:H-...
journal article 2021
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Ripepi, D. (author), Zaffaroni, R. (author), Schreuders, H. (author), Boshuizen, B. (author), Mulder, F.M. (author)
Direct electrochemical nitrogen reduction holds the promise of enabling the production of carbon emission-free ammonia, which is an important intermediate in the fertilizer industry and a potential green energy carrier. Here we show a strategy for ambient condition ammonia synthesis using a hydrogen permeable nickel membrane/electrode that...
journal article 2021
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Bannenberg, L.J. (author), Schreuders, H. (author), Dam, B. (author)
Hydrogen detection in a reliable, fast, and cost-effective manner is a prerequisite for the large-scale implementation of hydrogen in a green economy. Thin film Ta<sub>1−y</sub>Pd<sub>y</sub> is presented as an effective optical sensing material with extremely wide sensing ranges covering at least 7 orders of magnitude in hydrogen pressure....
journal article 2021
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Bannenberg, L.J. (author), Boshuizen, B. (author), Nugroho, Ferry Anggoro Ardy (author), Schreuders, H. (author)
Catalyzing capping layers on metal hydrides are employed to enhance the hydrogenation kinetics of metal hydride-based systems such as hydrogen sensors. Here, we use a novel experimental method to study the hydrogenation kinetics of catalyzing capping layers composed of several alloys of Pd and Au as well as Pt, Ni, and Ru, all with and without...
journal article 2021
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Bannenberg, L.J. (author), Schreuders, H. (author), Kim, H.J. (author), Sakaki, Kouji (author), Hayashi, Shigenobu (author), Ikeda, Kazutaka (author), Otomo, Toshiya (author), Dam, B. (author), Asano, Kohta (author)
Metal hydrides may play a paramount role in a future hydrogen economy. While most applications are based on nanostructured and confined materials, studies considering the structural response of these materials to hydrogen concentrate on bulk material. Here, using in situ in- and out-of-plane X-ray diffraction and reflectometry, we study the fcc ...
journal article 2021
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Chaykina, D. (author), Nafezarefi, F. (author), Colombi, G. (author), Cornelius, S. (author), Bannenberg, L.J. (author), Schreuders, H. (author), Dam, B. (author)
Thin films of rare earth metal oxyhydrides show a photochromic effect, the precise mechanism of which is yet unknown. Here, we made thin films of NdH3-2xOx and show that we can change the band gap, crystal structure, and photochromic contrast by tuning the composition (O2-:H-) via the sputtering deposition pressure. To protect these films...
journal article 2021
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Bannenberg, L.J. (author), Boelsma, C. (author), Asano, Kohta (author), Schreuders, H. (author), Dam, B. (author)
Hydrogen is playing a key role in the transition to a sustainable economy and in a variety of industrial processes. For its safe handling, the detection of hydrogen in a fast, reliable and accurate manner is crucial. Thin film metal hydride based optical hydrogen sensors provide an attractive option to sense hydrogen in a variety of conditions...
journal article 2020
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Griessen, Ronald (author), Boelsma, Christiaan (author), Schreuders, H. (author), Broedersz, Chase P. (author), Gremaud, Robin (author), Dam, B. (author)
Enthalpy-entropy compensation (EEC) is very often encountered in chemistry, biology and physics. Its origin is widely discussed since it would allow, for example, a very accurate tuning of the thermodynamic properties as a function of the reactants. However, EEC is often discarded as a statistical artefact, especially when only a limited...
journal article 2020
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Cornelius, S. (author), Colombi, G. (author), Nafezarefi, F. (author), Schreuders, H. (author), Heller, R. (author), Munnik, Frans (author), Dam, B. (author)
Thin films of rare-earth (RE)-oxygen-hydrogen compounds prepared by reactive magnetron sputtering show a unique color-neutral photochromic effect at ambient conditions. While their optical properties have been studied extensively, the understanding of the relationship between photochromism, chemical composition, and structure is limited....
journal article 2019
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Nafezarefi, F. (author), Cornelius, S. (author), Nijskens, J. (author), Schreuders, H. (author), Dam, B. (author)
Thin films of yttrium oxy-hydride have interesting, reversible photochromic properties, the origin of which is poorly understood. To investigate the role of point defect mobility, we probed the effect of lattice contraction as induced by the addition of zirconium. Interestingly, we find no loss of photochromic contrast for Y <sub>1-z</sub>...
journal article 2019
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