Environmentally Sensitive Luminescence Reveals Spatial Confinement, Dynamics, and Their Molecular Weight Dependence in a Polymer Glass

Polymer glasses have an irregular structure. Among the causes for such complexity are the chemically distinct chain end groups that are the most abundant irregularities in any linear polymer. In this work, we demonstrate that chain end induced defects allow polymer glasses to create confined environments capable of hosting small emissive...

Cure-induced residual stresses for warpage reduction in thermoset laminates

The paper addresses the role played by the cure stage of a vacuum assisted resin transfer molding process in residual stresses generation. The Airstone 780E epoxy resin and Hardener 785H system broadly used in the wind turbine blade industry has been used in this study. The viscous–elastic properties of the resin have been characterized and...

Color-Based Optical Detection of Glass Transitions on Microsecond Timescales Enabled by Exciplex Dynamics

Every measurement technique operates on a given timescale and measurements using emissive small molecule sensors are no exception. A family of luminescent sensors providing first optical characterization of dynamic phenomena in polymers at a timescale of several microseconds is described. This performance originates from the dynamics...

Development of PlastoLock overtube with temperature controlled rigidity for colonoscopy

To diagnose and treat colon cancer a colonoscopy is usually performed. Current colonoscopy is performed by advancing a colonoscope (scope) through the tortuous colon. However, the flexible scope often buckles when advanced. This can cause discomfort and pain for the patient and can make the examination of the colon difficult for the endoscopist....

Forcefields based molecular modeling on the mechanical and physical properties of emeraldine base polyaniline

Molecular dynamics (MD) and molecular mechanical (MM) analysis are carried out to provide reliable and accurate model for emeraldine base polyaniline. This study validate the forcefields and model with the physical and mechanical properties of the polyaniline. The temperature effects on non-bond energy, potential energy and solubility parameter...

Spatially periodic liquid crystal director field appearing in a photonic crystal template pectroscopy

Active tuning of photonic crystals can be achieved by filling the porous structures with liquid crystals. Here, the director field in macropores was studied by fluorescence confocal polarizing microscopy. For this purpose, the photonic crystal was infiltrated with a glass-forming liquid crystalline polymer, the sample was cooled below the glass...

Glassy behavior of a two-dimensional electron system in Si in parallel magnetic fields

Studies of low-frequency resistance noise show that the glassy freezing of the two-dimensional electron system (2DES) in Si in the vicinity of the metal-insulator transition (MIT) persists in parallel magnetic fields B of up to 9 T. At low B, both the glass transition density ng and nc, the critical density for the MIT, increase with B such that...

Finite-size effects on the vortex-glass transition in thin YBa2Cu3O7-d films

Superconducting phase of YBa 2Cu 3O 7- delta films in high magnetic fields: Vortex glass or Bose glass