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Griessen, Ronald (author), Dam, B. (author)In many experimental investigations of thermodynamic equilibrium or kinetic properties of series of similar reactions it is found that the enthalpies and entropies derived from Van ′t Hoff or Arrhenius plots exhibit a strong linear correlation. The origin of this Enthalpy-Entropy compensation, which is strongly related to the coalescence...journal article 2021
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Single Quality Factor for Enthalpy-Entropy Compensation, Isoequilibrium and Isokinetic RelationshipsGriessen, Ronald (author), Boelsma, Christiaan (author), Schreuders, H. (author), Broedersz, Chase P. (author), Gremaud, Robin (author), Dam, B. (author)Enthalpy-entropy compensation (EEC) is very often encountered in chemistry, biology and physics. Its origin is widely discussed since it would allow, for example, a very accurate tuning of the thermodynamic properties as a function of the reactants. However, EEC is often discarded as a statistical artefact, especially when only a limited...journal article 2020