Fast-charge high-voltage layered cathodes for sodium-ion batteries

Sodium-ion batteries have not only garnered substantial attention for grid-scale energy storage owing to the higher abundance of sodium compared with lithium, but also present the possibility of fast charging because of the inherently higher sodium-ion mobility. However, it remains a phenomenal challenge to achieve a combination of these...

Designing lithium halide solid electrolytes

All-solid-state lithium batteries have attracted widespread attention for next-generation energy storage, potentially providing enhanced safety and cycling stability. The performance of such batteries relies on solid electrolyte materials; hence many structures/phases are being investigated with increasing compositional complexity. Among the...

Chemical short-range disorder in lithium oxide cathodes

Ordered layered structures serve as essential components in lithium (Li)-ion cathodes^1–3. However, on charging, the inherently delicate Li-deficient frameworks become vulnerable to lattice strain and structural and/or chemo-mechanical degradation, resulting in rapid capacity deterioration and thus short battery life^2,4....

Predominant P3-Type Solid-Solution Phase Transition Enables High-Stability O3-Type Na-Ion Cathodes

Layered O3-type oxides are one of the most promising cathode materials for Na-ion batteries owing to their high capacity and straightforward synthesis. However, these materials often experience irreversible structure transitions at elevated cutoff voltages, resulting in compromised cycling stability and rate performance. To address such...

Slight Multielement Doping-Induced Structural Order-Disorder Transition for High-Performance Layered Na-Ion Oxide Cathodes

To realize concurrently the high-energy density and excellent cycling stability, maximum utilization of redox couple, minimization of detrimental phase transition, and structural degradation of O3-type layered oxide cathodes are critical for developing Na-ion batteries. Ni²⁺/Ni⁴⁺ redox couple showing multielectron...