Controlling the Morphology of Barrel-Shaped Nanostructures Grown via CuZn Electro-Oxidation

Herein, we report a feasible method for forming barrel-like hybrid Cu(OH)₂-ZnO structures on α-brass substrate via low-potential electro-oxidation in 1 M NaOH solution. The presented study was conducted to investigate the electrochemical behavior of CuZn in a passive range (−0.2 V–0.5 V) and its morphological changes that occur...

Morphology and photoluminescence of nanostructured oxides grown by copper passivation in aqueous potassium hydroxide solution

Copper foil was anodized in 1 M KOH at potentials ranging from −400 to −100 mV vs. Ag|AgCl electrode. Cyclic voltammetry showed a distinct peak with a maximum at around −150 mV. For anodizing at −100 and −200 mV, nanowires with diameters of ca. 19 and 24 nm respectively were found to be grown. Moreover, photoluminescence and X-ray diffraction...