Microstructural self-healing of bituminous materials: Combined experimental and numerical study

Bituminous materials form a class of materials that possess the intrinsic ability to selfheal. This self-healing capability is evidenced by the observation that the service life of these materials ‘in the field’ exceeds the service life as predicted by standard mechanical laboratory tests. This mismatch between laboratory prediction and field...

Understanding the molecular mechanisms involved in the interfacial self-healing of supramolecular rubbers

Supramolecular rubbers based on 2-aminoethylimidazolidone and fatty acids with epoxy crosslinks have been shown to self-heal via multiple hydrogen bonding sites. In this work, several tools are used to investigate the molecular mechanisms taking place at the interface to understand cohesive healing in these polymers. The quantification of self...