Liquid-Liquid-Gas Triphasic Hydrogenation of Bicarbonate to Formate in a Continuous Flow Tubular Reactor

Multiphasic reaction of bicarbonate hydrogenation to form formate using homogeneous Ru PNP pincer catalyst in a continuous flow tubular reactor is reported. The reaction system consists of three phases. Catalyst is dissolved in toluene while potassium bicarbonate is dissolved in water. The significance of efficient mixing among the organic...

Selectivity control between reverse water-gas shift and fischer-tropsch synthesis in carbon-supported iron-based catalysts for CO₂ hydrogenation

CO₂ hydrogenation to chemicals and fuels has the potential to alleviate CO₂ emissions and displace fossil resources simultaneously via consecutive RWGS and FTS reactions, also known as CO₂-FTS. As Fe-based catalysts are active and selective for both reactions, their bifunctionality requires a delicate balance...

Combining Atomic Layer Deposition with Surface Organometallic Chemistry to Enhance Atomic-Scale Interactions and Improve the Activity and Selectivity of Cu-Zn/SiO₂ Catalysts for the Hydrogenation of CO₂ to Methanol

The direct synthesis of methanol via the hydrogenation of CO₂, if performed efficiently and selectively, is potentially a powerful technology for CO₂ mitigation. Here, we develop an active and selective Cu-Zn/SiO₂ catalyst for the hydrogenation of CO₂ by introducing copper and zinc onto...

Combined capture and reduction of CO₂ to methanol using a dual-bed packed reactor

Recently, carbon capture and reduction (CCR) technology has gained interest to directly convert CO₂ to value-added products without requiring purification of CO₂ and its subsequent transportation. CCR to methanol in one dual function material (DFM) poses mechanistic and kinetic challenges. To counteract this, a process...

Bifunctionality of Re Supported on TiO₂ in Driving Methanol Formation in Low-Temperature CO₂ Hydrogenation

Low temperature and high pressure are thermodynamically more favorable conditions to achieve high conversion and high methanol selectivity in CO₂ hydrogenation. However, low-temperature activity is generally very poor due to the sluggish kinetics, and thus, designing highly selective catalysts active below 200 °C is a great...

CO₂ hydrogenation for the production of higher alcohols: Trends in catalyst developments, challenges and opportunities

Higher alcohol (HA) synthesis via the hydrogenation of CO₂ constitutes a relatively new and exciting field of research that has the potential to help towards the de-carbonization of the energy sector. The process poses formidable challenges, as it demands the formation of at least one C-C bond, when CO₂ is...

Direct and continuous conversion of flue gas CO₂ into green fuels using dual function materials in a circulating fluidized bed system

Carbon capture and utilization (CCU) technologies, such as CO₂ methanation, generally require energy-intensive CO₂ capture and separation processes prior to catalytic CO₂ conversion. In contrast, integrated CO₂ capture and reduction (CCR) technologies that use dual function materials (DFM) can...

Sorption enhanced catalysis for CO₂ hydrogenation towards fuels and chemicals with focus on methanation

Hydrogen produced by the electrolysis of water using sustainable electricity will play an increasingly important role as an energy and a feedstock vector. Shifting from fossil to renewable resources means that new industrial platforms have to be set up to provide carbon-based fuels and bulk base chemicals to replace the current fossil...

Lewis acidic supports promote the selective hydrogenation of carbon dioxide to methyl formate in the presence of methanol over Ag catalysts

Silica-supported silver nanoparticles exhibit outstanding efficiency in the CO₂ hydrogenation to methyl formate in the presence of methanol under high pressure. Here, we show that ZrO₂ and Al₂O₃ supports significantly increase the catalyst activity, in line with their higher Lewis acidity. The...

Continuous Hydrogenation of Carbon Dioxide to Formic Acid and Methyl Formate by a Molecular Iridium Complex Stably Heterogenized on a Covalent Triazine Framework

Continuous synthesis of formic acid and methyl formate via CO₂ hydrogenation is demonstrated using a molecular iridium complex stably immobilized on a solid covalent triazine framework (CTF) under high-pressure conditions. Compared to formic acid synthesis, methyl formate synthesis is advantageous to enhance the selectivity and...