Self-healing and corrosion-sensing coatings based on pH-sensitive MOF-capped microcontainers for intelligent corrosion control

Organic coatings are one of the most used and versatile technologies to mitigate corrosion of metals. However, organic coatings are susceptible to defects and damages that may not be easily detected. If not repaired timely, these defects may develop into major coating failures due to corrosion occurring in the damaged region, thereby limiting...

Smart protective coatings with self‐sensing and active corrosion protection dual functionality from pH-sensitive calcium carbonate microcontainers

Herein, we report the development of a self-sensing and active corrosion protection coating which incorporates pH-sensitive multilayer chitosan/alginate-covered CaCO₃ microcontainers containing 1,10-phenanthrolin-5-amine (APhen). The microcontainers can respond to pH variation to release APhen which serves not only as a corrosion...