Advances on methane reforming in solid oxide fuel cells

With the demand for anticipated green hydrogen and power production, novel and upgraded catalytic processes are desired for more effective utilization of precious natural resources. Methane steam reforming is an advanced and matured technology for converting methane to hydrogen and syngas. As a renewable energy resource containing a large...

Solid oxide fuel cells for ships: System integration concepts with reforming and thermal cycles

For decades, ships have been propelled by diesel engines. However, there are increasing concerns about their environmental impact. Fuel cells can provide an alternative to convert fuels directly into electricity, with high efficiencies and without hazardous emissions.<br/>Solid oxide fuel cells have a ceramic membrane, which functions at high...

Dynamic modelling of a direct internal reforming solid oxide fuel cell stack based on single cell experiments

Direct internal reforming enables optimal heat integration and reduced complexity in solid oxide fuel cell (SOFC)systems, but thermal stresses induced by the increased temperature gradients may inflict damage to the stack. Therefore, the development of adequate control strategies requires models that can accurately predict the temperature...

On direct internal methane steam reforming kinetics in operating solid oxide fuel cells with nickel-ceria anodes

Major operating challenges remain to safely operate methane fuelled solid oxide fuel cells due to undesirable temperature gradients across the porous anode and carbon deposition. This article presents an experimental study on methane steam reforming (MSR) global kinetics for single operating SOFCs with Ni-GDC (gadolinium doped ceria) anodes...