When all intermetallics dealloy in AA2024-T3: Quantifying early stage intermetallic corrosion kinetics under immersion

A hyphenated optical-electrochemical technique and image analysis protocol is used to quantify global and local (intermetallic) corrosion process and kinetics. Our findings reveal an early stage (< 60 s) composition-dependent hierarchical local activation of all IMs that can be attributed to IM dealloying. This is followed by local...

In-situ nanoscopic observations of dealloying-driven local corrosion from surface initiation to in-depth propagation

Dealloying is involved in materials science responsible for fabrication of nanoscale structures beneficially but for corrosion degradations detrimentally. Detailed understanding related to the latter is critical for designing corrosion-resistance alloys and dedicated inhibition systems. Thus, direct nanoscopic observations of nano-structural...

Dealloying-driven local corrosion by intermetallic constituent particles and dispersoids in aerospace aluminium alloys

Nanoscopic characterization of heterogeneous intermetallic particles (IMPs) which microstructurally and compositionally evolve during local corrosion is crucial in unravelling the mechanisms and sequence of initial and local corrosion events. Herein, we study site-specific initiation events focused on microscopic constituent intermetallic...