Carbon-Iron Electron Transport Channels in Porphyrin–Graphene Complex for ppb-Level Room Temperature NO Gas Sensing

It is a great challenge to develop efficient room-temperature sensing materials and sensors for nitric oxide (NO) gas, which is a biomarker molecule used in the monitoring of inflammatory respiratory diseases. Herein, Hemin (Fe (III)-protoporphyrin IX) is introduced into the nitrogen-doped reduced graphene oxide (N-rGO) to obtain a novel...

Squeeze-Film Effect on Atomically Thin Resonators in the High-Pressure Limit

The resonance frequency of membranes depends on the gas pressure due to the squeeze-film effect, induced by the compression of a thin gas film that is trapped underneath the resonator by the high-frequency motion. This effect is particularly large in low-mass graphene membranes, which makes them promising candidates for pressure-sensing...

Investigation of multi-layered graphene/silicon Schottky junction in oxidizing atmosphere

In this study, we investigate a Schottky junction based on solution-processed multilayered graphene (MLG). We present a rectifying device obtained with a straightforward approach, that is drop-casting a few microliters of MLG solution simultaneously onto Si, Si-SiO2 and Si-SiO2-Cr/Au surface. Monitoring the modulation of Schottky barrier...

Functionalisation of Multi-Layer Graphene-Based Gas Sensor by Au Nanoparticles

A novel gas sensor based on multi-layered graphene (MLG) functionalised with gold nanoparticles (Au-NPs) is presented. We demonstrate for the first time that: (1) the signal saturates during the analyte exposure, something which does not occur in the pristine material and in graphene-based gas sensors in general; (2) the sign of the device...

Analysis of a calibration method for non-stationary CVD multi-layered graphene-based gas sensors

Limitations such as lack of detected stationary signal and slow signal recovery after detection currently affect graphene-based chemi-sensors operating at room temperature. In this work, we model the behavior of a sensor in a test chamber having limited volume and simulating the environmental conditions. From this model, we mathematically derive...

Dynamics of interacting graphene membranes

Micro and nanomechanical sensors are indispensable in modern consumer electronics, automotive and medical industries. Gas pressure sensors are currently the most widespread membrane-based micromechanical sensors. By reducing their size, their unit costs and energy consumption drops, making them more attractive for integration in new applications...

Graphene gas pumps

We report on the development of a pneumatically coupled graphene membrane system, comprising of two circular cavities connected by a narrow trench. Both cavities and the trench are covered by a thin few-layer graphene membrane to form a sealed dumbbell-shaped chamber. Local electrodes at the bottom of each cavity allow for actuation of each...

Low Temperature CVD Grown Graphene for Highly Selective Gas Sensors Working under Ambient Conditions

In this paper we report on gas sensors based on graphene grown by Chemical Vapor Deposition at 850 °C. Mo was used as catalyst for graphene nucleation. Resistors were directly designed on pre-patterned Mo using the transfer-free process we recently developed, thus avoiding films damage during the transfer to the target substrate. Devices...

Colorimetry Technique for Scalable Characterization of Suspended Graphene

Previous statistical studies on the mechanical properties of chemical-vapor-deposited (CVD) suspended graphene membranes have been performed by means of measuring individual devices or with techniques that affect the material. Here, we present a colorimetry technique as a parallel, noninvasive, and affordable way of characterizing suspended...